Ionically Conducting Gel Polymers Electrolytes.

Abstract

During this period the activities have been focused on the preparation and the characterization of the first set of polymeric electrolyte samples to be sent to the U.S. ARL, Ft. Monmouth, NJ. This set is constituted by an adequate quantity of samples with the following molar composition: (1) PAN 16/ PC 23/ EC 56.5/ LiClO4 4.5; (2) PAN 16/ PC 23/ EC 56.5/ LiAsF6 4.5; (3) PAN 16/ PC 23/ EC 56.5/ Li-Imide 4.5. These samples have been prepared following the preparative route described later in the text and characterized by determining ionic conductivities, cationic transference numbers and the electrochemical stability windows. All the preparation procedures of the gel electrolytes and the related electrochemical measurements were carried out in an Argon filled glove box whose atmosphere had a moisture content constantly lower than 5 ppm. jg p1

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1995
Accession Number
ADA303718

Entities

Organizations

  • Sapienza University of Rome

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Synthesis
  • Chemistry
  • Conductivity
  • Decomposition
  • Electrical Conductivity
  • Electrolytes
  • Frequency Response
  • High Energy
  • Ionic Liquids
  • Ions
  • Lithium Batteries
  • Measurement
  • Membranes
  • Moisture Content
  • Perchlorates
  • Physical Chemistry

Fields of Study

  • Materials science

Readers

  • Aerospace Test and Evaluation
  • Electrochemical Engineering/ Fuel Cell Technologies