Static and Mobile Polymer Surfaces of Well Defined Structure.

Abstract

Photoresponsive monolayers were prepared by the chemisorption of azobenzene-containing molecules to silicate substrates. A reversible change in the water contact angle was observed upon UV irradiation. Neutron reflectometry was used to probe protein adsorption to monolayers. The adsorption of human serum albumin was observed for amine- and methyl-terminated monolayers. Molecular dynamic simulations indicated directions for the next generation of synthetic efforts; the ideal placement for the azobenzene group is near the tail or head of the surface-reactive molecule. jg p1

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Document Details

Document Type
Technical Report
Publication Date
Nov 15, 1995
Accession Number
ADA303928

Entities

People

  • Mark D Foster
  • Wayne L. Mattice
  • William J. Brittain

Organizations

  • University of Akron

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Adsorption
  • Albumins
  • Azobenzenes
  • Films
  • Molecular Dynamics
  • Monomolecular Films
  • Neutron Reflectometry
  • Polymers
  • Proteins
  • Reflectometry
  • Reversible
  • Scientists
  • Self Assembled Monolayers
  • Simulations
  • X Rays
  • X-Ray Reflectometry

Fields of Study

  • Chemistry
  • Physics

Readers

  • Electrochemical Surface Science
  • Polymer Science and Technology
  • Thin Film Deposition Science.