Thermochemistry of Polybenzimidazole Foams,

Abstract

Results are presented of a study of an automatic polybenzimidazole (PBI) polymer. This study included an analysis of the low-boiling, high-boiling, and solid residue fractions resulting from the pyrolysis and nonflaming oxidative degradation of PBI polymer at temperatures up to 1000 deg C. Both pyrolysis and nonflaming combustion were carried out in a thermoanalyzer, and the effluent gases were trapped on a porous polymer adsorbent. The degradation process was quenched at several intermediate temperatures and the volatile products were analyzed using gas chromatagraphic-mass spectrometric techniques. The solid residues and the virgin polymer were characterized by elemental analysis, and the high-boiling fraction was investigated by chemical-ionization mass spectrometry. jg p3

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1976
Accession Number
ADA306029

Entities

People

  • D. A. Chatfield
  • D. J. Wendel
  • I. N. Einhorn

Organizations

  • University of Utah

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Aging (Materials)
  • Alkenes
  • Body Weight
  • Carbon Monoxide
  • Chemistry
  • Combustion
  • Dielectric Gases
  • Free Radicals
  • Hydrogen Cyanide
  • Mass Spectrometry
  • Material Degradation Processes
  • Materials
  • Materials Processing
  • Nitriles
  • Polymer Degradation
  • Pyrolysis
  • Spectra

Readers

  • Analytical Chemistry
  • Polymer Science and Technology