Aging of Polymers and Composites.

Abstract

The microchemical changes produced during the aging of the resin system, MY720 (Ciba-Geigy) cured with Eporal (Ciba-Geigy), were studied by the combined use of chemiluminescence, vaporization gas chromatography (and mass spectrometry), precision abrasion mass spectrometry, and stress mass spectrometry. Resin coupons were aged at ambient, 85 deg C and 150 deg C in dry and moist atmospheres in the presence and absence of an external tensile stress (up to 50% of the ultimate tensile stress). The chemiluminescence peak intensity which occurs at a temperature change was found to be an inverse function of the aging time for a given set of environmental parameters. Propenal, a low-temperature decomposition product of the resin, may be related to the chemiluminescence and aging processes. jg p3 &4

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Document Details

Document Type
Technical Report
Publication Date
Jul 21, 1981
Accession Number
ADA306067

Entities

People

  • C. J. Wolf
  • D. L. Fanter
  • M. A. Grayson

Tags

Communities of Interest

  • Energy and Power Technologies
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Body Weight
  • Brushless Dc Motors
  • Chemical Analysis
  • Chemical Reactions
  • Chemistry
  • Climate Change
  • Composite Materials
  • Gas Chromatography
  • Low Temperature
  • Mass Spectrometry
  • Materials
  • Materials Laboratories
  • Materials Science
  • Mechanical Properties
  • Military Research
  • Tensile Strength
  • Tensile Stress

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Polymer Science and Engineering.