Obtaining and Transferring Soils for In-Vial Analysis of Volatile Organic Compounds.

Abstract

The ability to retain volatile organic compounds (VOCs) while collecting and transferring intact soils for in-vial analysis was evaluated with field and laboratory samples. Experiments were designed to assess if VOC concentrations are maintained in an intact soil sample when (1) held for under an hour in a metal core liner, (2) held for days in a metal core liner sealed with TFE-flourocarbon sheets or aluminum foil (ASTM D4547-91), (3) held for less than 2 minutes in a plastic bag after extruding from a sampling device, and (4) immediately transferred to an empty vial to which a solvent was added later. Results indicate that these procedures are all highly susceptible to volatilization losses. To maintain site-representative VOC concentrations, collection of soil samples for in-vial analysis should occur within minutes of exposing a fresh surface by using a device that limits soil structure disruption and exposure.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1996
Accession Number
ADA306918

Entities

People

  • Alan D. Hewitt
  • Nicole J. Lukash

Organizations

  • Cold Regions Research and Engineering Laboratory

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Alkenes
  • Aluminum
  • Aluminum Foil
  • Cold Regions
  • Composite Materials
  • Ecology
  • Engineering
  • Environmental Protection
  • Gas Chromatography
  • Hermetic Seals
  • Hydrocarbons
  • Materials
  • Metals
  • Organic Compounds
  • Sampling
  • Test Methods
  • Volatile Organic Compounds

Readers

  • Analytical Chemistry
  • Geotechnical Engineering.
  • Polymer Science and Engineering.