Properties of Solid Polymer Electrolyte Fluorocarbon Film.

Abstract

The ionic fluorocarbon film used as the solid polymer electrolyte in hydrogen/oxygen fuel cells was found to exhibit delamination failures. Polarized light microscopy of as-received film showed a lined region at the center of the film thickness. It is shown that these lines were not caused by incomplete saponification but probably resulted from the film extrusion process. The film lines could be removed by an annealing process. Chemical, physical, and tensile tests showed that annealing improved or sustained the water contents, spectral properties, thermo-oxidative stability, and tensile properties of the film. The resistivity of the film was significantly decreased by the annealing process.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1973
Accession Number
ADA307202

Entities

People

  • William B. Alston

Organizations

  • Glenn Research Center

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Acids
  • Alkenes
  • Diffraction
  • Emission Spectroscopy
  • Failure Mode And Effect Analysis
  • Films
  • Fluoropolymers
  • Fuel Cells
  • Glass Transition Temperature
  • Heat Treatment
  • Indicator Dyes
  • Polymeric Films
  • Sodium Hydroxide
  • Tensile Properties
  • Tensile Strength
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Materials science

Readers

  • Mechanical Engineering/Mechanics of Materials.
  • Polymer Science and Technology
  • Thin Film Deposition Science.

Technology Areas

  • Biotechnology