Synthesis Characterization and X-Ray Structural Study of a Dinuclear Organoindium Phosphide Complex with Two Different Phosphide Moieties (Me3CCH2)2InP(t-Bu)2 In(CH2CMe3)2PPh2.

Abstract

An organoindium phosphide which incorporates two phosphido moieties in the same molecule (Me3CCH2)2InP(t-Bu)2In(CH2CMe3)2PPh2, 1, has been synthesized in good yield from (Me3CCH2)2InP(t-Bu)22 and (Me3CCH2)2InPPh2 in pentane solution and fully characterized. The compound exists as a single compound in the solid state according to an X-ray structural study but is in equilibrium with the starting compounds in benzene solution according to (1)H and (31)P NMR spectral data. p1

Open PDF

Document Details

Document Type
Technical Report
Publication Date
May 03, 1996
Accession Number
ADA308075

Entities

People

  • Charles H. Lake
  • Melvyn Rowen M.R. Churchill
  • O. T. Beachley Jr.
  • Sun-hua L. Chao

Organizations

  • University at Buffalo

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Chemical Shifts
  • Chemistry
  • Controlled Atmospheres
  • Crystals
  • Diffractometers
  • Dihedral Angle
  • Equations
  • Materials
  • Military Research
  • New York
  • Physical Properties
  • Resonance
  • Spectra
  • United States
  • United States Government
  • Vacuum Distillation
  • X Rays

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry