Silver Oxide/Zinc Rechargeable Lithium Cells: A Comparison with High Energy Density Lithium/Lithium Cobalt Oxide.

Abstract

Commercial, 30-ampere-hour Silver Oxide/Zinc (AgO/Zn) cells were evaluated for cycle life and charge retention. Results were compared to recently developed 30-ampere-hour Lithium/Lithium Cobalt Oxide (Li/Li(x)CoO2) cells. Prior to cycling at -2 deg C, +23 deg C, and +35 deg C, some cells were stored up to three months under four storage conditions: +23 deg C charged, +23 deg C discharged, +35 deg C charged, and +35 deg C discharged. Cells were discharged at the six hour rate. Cycling continued until discharge capacity fell to 25 Ampere-hour (Ah) at room temperature, cells delivered about 40 watt-hours per pound (Wh/lb). Performance improved at +35 deg C but severely degraded at -2 deg C. The lithium cells provided almost 60-Wh/lb. Silver Oxide/Zinc cells stored charged at +23 deg C for three months lost one-third of their initial capacity; those stored at +35 deg C lost half of their initial capacity. Even slow charging could not restore the loss. Discharged cells stored better, but capacity fell off more rapidly.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1995
Accession Number
ADA308902

Entities

People

  • C. J. Kelly
  • C. W. Fleischmann
  • D. L. Chua
  • H-p. W. Lin
  • P. H. Smith

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Cathodes
  • Cobalt
  • Cobalt Oxides
  • Crystal Lattices
  • Energy
  • Engineering
  • High Energy
  • Malfunctions
  • Military Research
  • Naval Warfare
  • New Hampshire
  • Silver Oxides
  • Surface Warfare
  • Underwater Vehicles
  • Vehicles
  • Warfare

Readers

  • Battery Technology and Engineering
  • Mathematics or Statistics