Investigation of Resin Systems for Improved Ablative Materials.

Abstract

This final report describes the work performed to advance the state of the art of resin matrices required for improved ablative materials for use with high energy fluorine containing liquid propellant systems. This experimental program was a continuation of a previously reported effort (NASA CR-54471) and consisted of a systematic materials development effort of resin synthesis and property determination of new and previously identified resin systems, optimization of composite processing parameters and fabrication and use testing of candidate ablative composites. Two new high char forming polymer systems were synthesized, fabricated and evaluated in composite form for ablative use effectiveness. These aromatic/heterocyclic polymer systems were designed to be processed readily with the evolution of minimum quantity of volatile matter during cure. As a consequence, low void, high strength composites were prepared which exhibited ablative performance (combination of dimensional stability, weight retention and resistance to thermal shock) superior to commercially available ablative materials when tested in a FLOX/methane torch combustion environment. Tested composites were prepared using Refrasil, graphite and carbon cloth and titanium diboride fibrous reinforcements.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1968
Accession Number
ADA309498

Entities

People

  • E. A. Burns
  • H. R. Lubowitz
  • J. F. Jones

Organizations

  • TRW Inc.

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Human Systems
  • Weapons Technologies

DTIC Thesaurus Topics

  • Ablative Materials
  • Anhydrides
  • Body Weight
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Composite Materials
  • Fabrication
  • Graphitic Materials
  • Laminates
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Materials Testing
  • Organic Chemistry
  • Test And Evaluation

Fields of Study

  • Materials science

Readers

  • Polymer Science and Engineering.
  • Reinforced Composite Materials
  • Systems Analysis and Design