Sol-Gel Based Electrochemical Biosensors.

Abstract

This work is based on the use of the sol-gel process to encapsulate biomolecules in a porous silicate matrix. The porosity of the matrix is such that small molecules and ions can readily diffuse into the materials while the much larger proteins remain trapped in the silicate network. Using this approach, it is possible to develop new types of solid state sensors which use the specificity of enzymes and proteins for binding of substrates or related molecules. The objective of our initial work has been to obtain electron transport from the redox center of an encapsulated enzyme (making use of redox-active molecules or mediators) so as to measure the electrochemical response of the doped sol-gel to an external analyte.

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Document Details

Document Type
Technical Report
Publication Date
Jun 18, 1996
Accession Number
ADA310507

Entities

People

  • B. C. Dave
  • Bruce S. Dunn
  • J. I. Zink
  • J. S. Valentine

Organizations

  • University of California, Los Angeles

Tags

DTIC Thesaurus Topics

  • Biomolecules
  • Biosensors
  • Detectors
  • Electrons
  • Materials
  • Molecules
  • Porosity
  • Silicates
  • Small Molecules
  • Sol Gel Processes
  • Substrates
  • Transport Ships

Readers

  • Electrochemical Surface Science
  • Molecular Genetics
  • Reinforced Composite Materials

Technology Areas

  • Biotechnology
  • Microelectronics