Simple Field Screening Method for White Phosphorus (P4) in Sediment.

Abstract

A simple field screening method to detect white phosphorus particles in sediment is described. A thin layer of wet sediment is heated until all water evaporates. The presence of white phosphorus is indicated by visual detection of the inflammation of white phosphorus particles that occurs at relatively low temperatures (less than 40 deg C) once a protective layer of water is removed. The field screening method consistently gave positive results for samples where solvent extraction followed by gas chromatography indicated white phosphorus concentrations above 1 micrograms/g. A more sophisticated method, based on solid-phase microextraction and gas chromotography determination, was also tested. Concentrations less than 1 microgram/kg were detectable.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1995
Accession Number
ADA311992

Entities

People

  • Carl Bouwkamp
  • Charles H. Racine
  • Charles M. Collins
  • Marianne E. Walsh
  • Philip G. Thorne

Organizations

  • Cold Regions Research and Engineering Laboratory

Tags

Communities of Interest

  • Human Systems
  • Weapons Technologies

DTIC Thesaurus Topics

  • Birds
  • Chromatographs
  • Chromatography
  • Cold Regions
  • Detection
  • Engineering
  • Extraction
  • Field Tests
  • Gas Chromatography
  • Low Temperature
  • Mass Spectrometry
  • Materials
  • Particles
  • Phase
  • Phosphorus
  • Solid Phases
  • Solvent Extraction

Readers

  • Analytical Chemistry
  • Atmospheric Remote Sensing.