High Nitrogen Explosives. Part 2. Dibenzo-1 ,3a,4,6a- Tetraazapentalenes and Benzo-1 2,3,4-Tetrazine-1,3-Dioxides.

Abstract

High nitrogen materials are sought as a potentially dense, powerful but insensitive explosive and propellant ingredients. Elucidation of the structure and chemistry of dibenzo-1 ,3a,4,6a-tetraazapentalenes has continued, with particular attention to a putative C12N12O12 derivative initially prepared at the University of New Orleans. This research contributed substantially to identification of the actual o-quinone hydrate structure, and explanation of the apparently anomalous explosive insensitivity of the material. Synthesis of the novel 5,7-dinitrobenzo-1 ,2,3,4-tetrazine-1,3-dioxide has been repeated, its structure has been confirmed, and preliminary evaluation of its explosive sensitivity has been completed.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1996
Accession Number
ADA313360

Entities

People

  • Karen L. Altmann
  • Lawrence H. Merwin
  • Richard Gilardi
  • William P. Norris
  • William S. Wilson

Organizations

  • Naval Air Warfare Center Weapons Division

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Energetic Materials
  • Explosive Ordnance Disposal
  • Explosives
  • Insensitive Explosives
  • Materials
  • Materials Laboratories
  • Materials Science
  • Measurement
  • Military Research
  • Nitrogen
  • Nitrogen Compounds
  • Nitrogen Oxides
  • Organic Chemistry
  • Rocket Oxidizers

Fields of Study

  • Chemistry

Readers

  • Environmental Engineering.
  • Organic Chemistry
  • Theoretical Analysis.