A Supramolecular Approach to the Mechanisims of Photomineralization of Hazardous Materials.

Abstract

Supramolecular photochemistry provides experimental tools and mechanistic concepts pertinent to the examination of the fate of Air Force chemicals and how they may be photochemically transformed into environmentally benign substances. This benefication process of converting AF chemicals to environmentally benign materials is termed mineralization. A 'biomimetic' strategy is adopted for which the laboratory model of benefication is based on processes occurring in nature. This biomimetic model provided us with the strategy of employing supramolecular photosystems to achieve the mineralization of AF chemicals via photosensitized degradation.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1996
Accession Number
ADA318384

Entities

People

  • Nicholas J. Turro

Organizations

  • Columbia University

Tags

Communities of Interest

  • Human Systems

DTIC Thesaurus Topics

  • Air Force
  • Air Force Facilities
  • Chemistry
  • Degradation
  • Electron Paramagnetic Resonance
  • Electron Transfer
  • Electrons
  • Fluoropolymers
  • Gas Turbines
  • Hazardous Materials
  • Materials
  • Mineralization
  • New York
  • Paramagnetic Resonance
  • Photochemical Reactions
  • Photochemistry
  • Turbines

Fields of Study

  • Chemistry
  • Environmental science

Readers

  • Aerospace logistics and air mobility.
  • Organic Chemistry
  • Systems Analysis and Design

Technology Areas

  • Biotechnology
  • Biotechnology - Bioremediation