Analysis of Natural Gas by FT-IR; Calibrations and Validations.

Abstract

A fast experimental protocol was established for the simultaneous determination of methane, ethane, propane, and butane in nitrogen from Fourier transform infrared (FT-IR) spectra. The method is based on correlations established between known gas compositions and their FT-IR spectra. The spectra were collected in the region of 4,000 to 400/cm through KBr windows in a 100-mm pathlength gas sample cell operating at 100, 300, 500, 700, and 1,000 mm Hg pressure. Correlation between blending partial pressure or GC-based analysis and FT-IR data produced squared correlation coefficients (R2) in excess of 0.9g. Total required analytical time is less than 2 minutes.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1997
Accession Number
ADA324665

Entities

People

  • George E. Fodor

Organizations

  • Southwest Research Institute

Tags

Communities of Interest

  • Autonomy
  • Energy and Power Technologies
  • Human Systems

DTIC Thesaurus Topics

  • Air Force
  • Blending
  • Calibration
  • Calorific Value
  • Chemistry
  • Coefficients
  • Combustion
  • Heat Of Combustion
  • Infrared Spectroscopy
  • Measurement
  • Natural Gas
  • Nitrogen
  • Partial Pressure
  • Research Facilities
  • Spectra
  • Spectroscopy
  • Validation

Fields of Study

  • Chemistry

Readers

  • Computational Modeling and Simulation
  • Organic Chemistry
  • Wave Propagation and Nonlinear Chaotic Dynamics.