Formation and Structural Characterization of the Mixed-Metal Pnicogen-Bridged Four-Membered Ring Compounds (Et2O)2LiMU-E(SiMe3)22GaH2, E=P, As.

Abstract

Two compounds with novel connectivities, (Et2O)2 LiMU-E(SiMe3)22 GaH2, E = P (1), As (2), formally lithium pnictidogallates, were synthesized in the reactions between LiGaH4 and E(SiMe3)3 in diethyl ether via trimethylsilane elimination.

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Document Details

Document Type
Technical Report
Publication Date
May 15, 1997
Accession Number
ADA325329

Entities

People

  • J. F. Janik
  • Jason A. Halfen
  • R. L. Wells
  • V. G. Young Jr.

Organizations

  • Duke University

Tags

Communities of Interest

  • C4I
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chemical Laboratories
  • Chemistry
  • Crystal Structure
  • Crystals
  • Diagrams
  • Elements
  • Equations
  • Group 13 Elements
  • Hydrogen
  • Materials
  • Military Research
  • Phosphorus Compounds
  • Single Crystals
  • Spectra
  • Spectroscopy
  • X Rays

Fields of Study

  • Chemistry

Readers

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