Phosphorus Containing Dendrimers: Surface Chemistry and Applications
Abstract
The synthesis of phosphorus containing dendrimers is described up to the fifth generation (96 terminal groups). The surface chemistry of these dendrimers allows the grafting of various functionalities such as phosphate (6 O-P(O)(OEt)2 groups), aminophosphate (up to 96 N-P(O)(OEt)2 groups), aminophosphite (up to 96 N-P(OEt)2 groups), functionalized phosphonate (up to 96 HC(OH)P(O)(OR)2 (R = Et, (CH2)11CH3), up to 96 HC(N-Pr)P(O)(OEt)2, or up to 48 CH=CH-P(O)(OEt)2), phosphorus ylide (6 C(O)CH=P(Ph)3), carboxylic acid (up to 24 CH=CH-C(O)OH), and tetraazamacrocycle (up to 12 cyclam). These surface functionalities have been chosen due to the well known properties of the corresponding monomers and/or polymers in various areas such as adhesives, flame retardants, fuel additives, sequestring agents.
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 01, 1997
- Accession Number
- ADA329172
Entities
People
- A. M. Caminade
- D. Prevote
- Jean-pierre Majoral
Organizations
- National Center for Scientific Research