Influence of Composition, Chain Architecture and Processing on Polymer Structure and Properties.

Abstract

This project concerned the fundamental understanding of processing-structure and structure-property relations in block copolymer and liquid crystalline polymer systems. Key to our studies was the availability of model materials which afforded opportunities via new chemical compositions and physical properties. Transmission electron microscopy, low voltage high resolution scanning electron microscopy, light microscopy and atomic force microscopy as well as wide and small angle x-ray scattering were the principal characterization tools. We also employed a special roll cast process to form highly textured samples for investigation of their physical properties. Principal research accomplishments are grouped into 6 areas: influence of architecture on phase behavior; development of experimental techniques; microphase separation in block copolymers; large strain deformation of single crystal thermoplastic elastomers; morphology and dynamic interaction of defects in polymer liquid crystals; and technology transitions.

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Document Details

Document Type
Technical Report
Publication Date
Jul 10, 1997
Accession Number
ADA329683

Entities

People

  • Edwin L. Thomas

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Biomedical And Dental Materials
  • Block Copolymers
  • Copolymers
  • Crystals
  • Electron Microscopy
  • Films
  • High Resolution
  • Liquid Crystals
  • Materials
  • Materials Science
  • Microscopy
  • Physical Properties
  • Polymeric Films
  • Polymers
  • Scanning Electron Microscopy
  • Transmission Electron Microscopy
  • X Rays

Fields of Study

  • Materials science

Readers

  • Polymer Science and Technology
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.

Technology Areas

  • Microelectronics