Absorption of Ultrasound in Organic Crystals.

Abstract

In this paper we present our expression for the transition rate for a molecule in an organic crystal to absorb three phonons of lattice energy into the lowest frequency molecular vibrational mode (O+l transition). Our model is a three dimensional simple cubic lattice with nearest neighbor central and noncentral forces between molecules situated at the lattice sites. After making some approximations we compare our expression with the transition rate determined from ultrasonic experiments on benzene, p-dichlorobenzene1 carbon tetrachloride, and cyclohexane and discuss the results, We also point out the improvement Our expression offers over the transition rate derived by Liebermann and used by other investigators.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1976
Accession Number
ADA330043

Entities

People

  • Denis F. Strenzwilk
  • Peter D. Yedinak

Organizations

  • Ballistic Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption
  • Acoustic Propagation
  • Chemistry
  • Computational Science
  • Crystal Lattices
  • Crystal Structure
  • Crystals
  • Cubic Lattices
  • Energy
  • Energy Transfer
  • Mechanics
  • Physics
  • Quantum Mechanics
  • Quantum Statistical Mechanics
  • Resonance Absorption
  • Solid State Physics
  • Ultrasounds

Readers

  • Organic Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.