Hexagonal II-VI Structures by Substrate Bandgap Engineering

Abstract

A synthesis procedure was developed for bulk ZnMgSSe, using metallic Mg and Se. This is done in the growth crucible in the growth system; this reduces contamination from exposure to the laboratory ambient. A growth run with 12% Mg and 8% S (nominal) concentrations was done using our zone melting technique in a non-seeding crucible. A 45 deg cross-section was made by cleaving; it appeared that one grain was about half of the 26 mm (average) diameter boule. No twins were visible at all. It is, of course, desirable to have twin-free material, but, even more importantly, the lack of twins is a strong indication of hexagonal material, a major goal of the program.

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Document Details

Document Type
Technical Report
Publication Date
Oct 08, 1997
Accession Number
ADA330085

Entities

People

  • Brian J. Fitzpatrick
  • Maria C. Tamargo

Tags

Communities of Interest

  • Advanced Electronics
  • Weapons Technologies

DTIC Thesaurus Topics

  • Ballistic Missiles
  • Band Gaps
  • Crucibles
  • Energy Bands
  • Engineering
  • Epitaxial Growth
  • Materials
  • Military Research
  • Molecular Beams
  • New York
  • Scattering
  • Semiconductors
  • Substrates
  • Technical Information Centers
  • Transition Temperature
  • X Rays
  • Zone Melting

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