Effect of a Warm, Moist Environment on JA2 Gun Propellant.

Abstract

Grains and sticks of JA2 propellant downloaded from a 1 2O-mm tank round that had been subjected to conditioning at high temperature and humidity were observed to be discolored and covered with an unknown liquid. Analysis of the propellant indicated a decrease in the nominal diethylene glycol dinitrate (DEGDN) plasticizer content. The nitroglycerine (NG) content was not observed to deviate significantly from its nominal level. The cause of the discoloration of the propellant was traced to its high moisture content. The liquid covering the material was determined to be a mixture of water and DEGDN. in follow-up experiments, it was determined that JA2 propellant can absorb an excess of 13 wt-% moisture. It was also learned that graphite glaze can reduce the tendency of a grain to absorb moisture for grains immersed in water. When conditioned in a high-humidity environment, graphite glaze appeared to have no effect on the level of moisture absorbance. It is suspected that graphite serves to plug pores on the surface of the propellant and thereby inhibit, but not prevent, moisture absorption.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1997
Accession Number
ADA331765

Entities

People

  • P. Sagear
  • R. Leffers
  • R. Pesce-rodriguez

Organizations

  • United States Army Research Laboratory

Tags

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Environment
  • Graphitic Materials
  • Gun Propellants
  • High Humidity
  • Humidity
  • Liquid Explosives
  • Mass Spectrometry
  • Materials
  • Materials Laboratories
  • Materials Science
  • Military Research
  • Moisture Content
  • Piezoelectric Crystals
  • Propellants
  • Spectra

Readers

  • Mathematics or Statistics
  • Polymer Science and Engineering.
  • Rocket Propulsion.