Optical Properties of Distyrylbenzene Chromophores and Their Segmented Copolymers

Abstract

A new segmented polymer (3) consisting of a distyrylbenzene chromophore separated by polyethylene glycol segments has been prepared by two independent methods: a novel, polymer analogous Mitsunobu reaction and conventional double displacement reaction. The polymer is soluble in a variety of organic solvents, forms excellent, optically clear films and exhibits strong fluorescence. The properties of the chromophore and the polymer, as well as the scope and limitations of the novel Mitsonobu polymerization are presented. Attempts to use polymer (3) in electroluminescent devices are also discussed.

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Document Details

Document Type
Technical Report
Publication Date
Dec 08, 1997
Accession Number
ADA332760

Entities

People

  • D. J. Sandman
  • Jayant Ram Kumar
  • Kexin Yang
  • N. Benfaremo
  • S. Tripathy

Organizations

  • University of Massachusetts Lowell

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Advanced Materials
  • Chemical Synthesis
  • Chemistry
  • Chromophores
  • Copolymers
  • Ethylene Glycol
  • Films
  • Fluorescence
  • Luminance
  • Materials
  • Materials Science
  • Optical Properties
  • Polyethylene Glycols
  • Polymerization
  • Polymers
  • Spectra
  • United States

Fields of Study

  • Chemistry

Readers

  • Polymer Science and Technology

Technology Areas

  • Microelectronics