Computer Simulations of Low Temperature High Energy Density Materials

Abstract

Solid hydrogen doped with energetic impurities may form the basis for HEDM to be used in rocket propulsion. A key research priority was therefore the largescale computer simulation of impurity diffusion and recombination in HEDM in order to better understand the reasons for its stability, or instability, as the case may be. The recombination of these atomic impurities is an extremely exothermic reaction, and therefore thermodynamically favored. Theoretical developments within our research group allowed for the (otherwise impossible) quantum dynamical simulation of these systems which was necessary to properly treat the problem. Classical molecular dynamics simulations, while less computationally challenging, predict qualitatively incorrect properties for low temperature liquid and solid hydrogen because of the highly quantum nature of hydrogen matrix, and are therefore inadequate.

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Document Details

Document Type
Technical Report
Publication Date
Mar 31, 1997
Accession Number
ADA332824

Entities

People

  • Gregory A. Voth

Organizations

  • University of Pennsylvania

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Chemistry
  • Computational Chemistry
  • Computer Simulations
  • Computers
  • Diffusion
  • Dynamics
  • Energy
  • Exothermic Reactions
  • High Energy
  • Hydrogen
  • Impurities
  • Instability
  • Low Temperature
  • Molecular Dynamics
  • Rocket Propulsion
  • Simulations

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Computational Modeling and Simulation
  • Quantum Chemistry

Technology Areas

  • Quantum Computing