Molecular Mechanisms of Biosynthesis of Metal-Binding PCs

Abstract

Our research during the project period was directed towards three fundamental aspects of PCs: (1) metal-chelation by PCs, (2) sulfide complexes of PCs and (3) biosynthesis of PCs. We have made thorough investigations of the metal-binding properties of PCs and published data that provides benchmark information on the Ag(1), Cu(1), Cd(2), Hg(2) and Pb(2)-binding characteristics of these plant metal binding peptides. We have carried out detailed investigations on the sulfide complexes of PCs (PCs) that profoundly influence the metal-binding capacity of these peptides. In addition, these complexes have the potential to be very useful reagents for the detoxification of a variety of organic contaminants. Using a complementation cloning strategy, we have isolated a gene that is required for Cd tolerance and PC production. Although this gene did not turn out to be PC synthase, it provides us a good picture of the role of heme biosynthesis in PC production.

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Document Details

Document Type
Technical Report
Publication Date
Oct 31, 1997
Accession Number
ADA335807

Entities

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  • Rajesh Mehra

Organizations

  • University of California, Riverside

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  • Advanced Electronics

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