Molecular Beam Epitaxial Growth and Characterization of Mismatched InGaAs and InAlAs Layers on InP

Abstract

Mismatched epitaxial layers of In(x)Ga(1-x)As and In(y)Al(1-y)As were grown on (001) InP by molecular beam epitaxy. The layers were characterized by a technique we developed known as variable azimuthal-angle ellipsometry. It reveals large optical anisotropy for many strained layers. We attribute the anisotropy to strain-induced surface roughening during growth. Samples were also characterized by high-resolution x-ray diffraction (HRXRD) to assess layer quality as well as composition and strain. HRXRD measurements reveal orthorhombic distortion of partially relaxed layers of InGaAs and InAlAs in tension or compression, with preferential strain relief in the 110 direction. We show that HRXRD epilayer peak width and interference fringes are sensitive, non-destructive criteria to judge the structural quality of strained heterostructures. For layers ranging from 300 to 10,000 A, with lattice mismatch of +/- 1% or less, the crystalline quality consistently remains high to thicknesses up to 3-9 times the Matthews-Blakeslee critical layer thickness. We investigated the thermal stability of these layers, using HRXRD to measure structural changes caused by high-temperature anneals. We also compared the electron mobility of modulation- doped heterostructures before and after annealing. Both techniques demonstrate that our high-quality strained layers are stable to temperatures of at least 800-859 deg C. We explain this result by the limited sources available for the nucleation of misfit dislocations. The findings are applied to the design and growth of high-performance pseudomorphic InAlAs /InGaAs /InP heterostructure field-effect transistors with layers exceeding the Matthews-Blakeslee limit.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1993
Accession Number
ADA342861

Entities

People

  • Brian R. Bennett

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Vapor Deposition
  • Energy Bands
  • Energy Gaps
  • Epitaxial Growth
  • Field Effect Transistors
  • Geometry
  • Materials
  • Materials Science
  • Measurement
  • Molecular Beams
  • Molecular Dynamics
  • Optical Properties
  • Semiconductors
  • Solid State Physics
  • Surface Chemistry
  • Three Dimensional
  • Two Dimensional

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene