Nuclear Magnetic Resonance (NMR) Procedure for the Characterization of HD Hydrolyates

Abstract

A useful and facile nuclear magnetic resonance (NMR) method for characterizing hydrolysates of HD (2,2'- dichlorodiethyl sulfide) has been developed. The method uses both H-1 and C-13 NMR to identify the major components (>0.1 mole%) in the hydrolysate and to determine the mole ratios of these compounds in solution. This NMR method is especially useful since no sample preparation is required, and all soluble compounds, including the polar and ionic hydrolysis products of HD, are easily observed This report outlines a step-by-step procedure for characterizing HD hydrolysates using NMR spectroscopy and describes, in detail, the analysis of a typical hydrolysate sample. Interpreted H-1 and C-13 spectra and reproducibility data are included as well as a list of representative NMR parameters for compounds typically present in the hydrolysates.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1998
Accession Number
ADA343542

Entities

People

  • Linda L. Szafraniec
  • William T. Beaudry

Organizations

  • Edgewood Chemical Biological Center

Tags

DTIC Thesaurus Topics

  • Chemical Analysis
  • Chemical Shifts
  • Chemical Warfare Agents
  • Chemistry
  • Electromagnetic Radiation
  • Frequency
  • Hydrolysis
  • Magnetic Fields
  • Magnetic Moments
  • Magnetic Resonance
  • Nuclear Magnetic Resonance
  • Repetition Rate
  • Resonance
  • Spectra
  • Spectrometers
  • Spectroscopy
  • Standards

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  • Environmental Engineering.
  • Materials Science and Engineering.
  • Molecular and Cellular Biochemistry