Electron Beam Manufacturable Composites for Space Applications

Abstract

This program investigated electron beam curing with three types of composite matrix resins for use in space applications. Cyanate ester and propargyl terminated resins were shown to undergo radiation-induced rearrangements and did not polymerize. Recommendations are included for chemical structures containing cyanates and acetylene groups that should not undergo rearrangement and thus should produce high molecular weight polymers. Cationic-initiated epoxy resins polymerized to high glass transition polymers were selected for fabrication of composites reinforced with an intermediate modulus carbon fiber. Those systems displayed mechanical and thermal properties equivalent to those of thermally cured composites with similar matrix resins even when electron beam cured at temperatures below -30 C. When optimized, electron beam curing at subambient temperatures will result in high performance composite structures for space applications with low, stress-free temperatures and improved dimensional stability.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1998
Accession Number
ADA344507

Entities

People

  • Andrea E. Hoyt
  • Larry A. Harrah
  • Ronald E. Allred

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alkenes
  • Alkynes
  • Chemical Products
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Composite Material Fabrication
  • Composite Materials
  • Energy Transfer
  • Ionizing Radiation
  • Materials
  • Materials Processing
  • Materials Science
  • Organic Chemistry
  • Quantum Yields

Fields of Study

  • Materials science

Readers

  • Polymer Science and Engineering.
  • Polymer Science and Technology
  • Reinforced Composite Materials

Technology Areas

  • Directed Energy
  • Microelectronics
  • Space