Vibrational Spectroscopic Identification of Protonation and Oxidation States of DMcT

Abstract

In this contribution we report some initial results of our solid phase vibrational spectroscopic study of 2,5-dimercapto-1,3,4-thiadiazole (DMcT) and derivatives representing its protonation and oxidation states. We have succeeded in assigning observed bands to modes that are diagnostically useful for studies concerning the electrochemical character of DMcT when used with polyaniline (Pan) as a composite cathode material in a secondary lithium ion cell. We also discuss the implications of the current study for our further investigations of the DMcT/Pan cathode.

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Document Details

Document Type
Technical Report
Publication Date
Jun 29, 1998
Accession Number
ADA348862

Entities

People

  • D. A. Buttry
  • E. Shouji
  • J. M. Pope
  • N. Oyama
  • T. Sotomura
  • Takaaki Sato

Organizations

  • University of Wyoming

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