Spectroscopic Determination of the Protonation and Oxidation States of 2,5-Dimercapto-l,3,4-thiadiazole

Abstract

The dimercaptan, 2,5-dimercapto-1,3,4-thiadiazole (DMcT) has been examined widely as a component in lithium secondary battery cathodes. However, spectroscopic studies of its behavior have been impeded by general uncertainty regarding its vibrational band assignments. Therefore, assignment of the structure and vibrational bands for DMcT and some derivatives is reported in this contribution.

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Document Details

Document Type
Technical Report
Publication Date
Jun 29, 1998
Accession Number
ADA348911

Entities

People

  • Daniel A. Buttry
  • Eiichi Shouji
  • John M. Pope
  • Kevin White
  • Toshitada Sato

Organizations

  • University of Wyoming

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Crystals
  • Energy Bands
  • Frequency
  • High Temperature
  • Materials
  • Molecules
  • Oxidation
  • Phase
  • Raman Spectra
  • Raman Spectroscopy
  • Resonance
  • Solid Phases
  • Spectra
  • Spectroscopy
  • Vibrational Spectra

Fields of Study

  • Chemistry

Readers

  • Electrochemical Surface Science
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.
  • Systems Analysis and Design