New Approaches to the Labeling of Estrogens Useful for PET (Predoctral Training Program).

Abstract

By incorporating a positron-emitting radionuclide into an estrogen receptor ligand, estrogen receptor-positive breast cancer can be visualized with Positron Emission Tomography (PET). in the search for improved estrogen receptor imaging agents, three isomers of 16-methoxyestradiol were synthesized via two synthetic routes, each utilizing methyl hypofluorite. The unusual chemistry of methyl hypofluorite provides a previously unexplored route for functionalizing the 16-position of estradiol and would provide a means of rapidly incorporating carbon-11 into biomolecules. The estrogen receptor binding affinities for these isomers determined these compounds to be ineffective imaging agents for the estrogen receptor.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1998
Accession Number
ADA350278

Entities

People

  • Stephanie D. Jonson

Organizations

  • University of Washington

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Alkanes
  • Alkenes
  • Breast Cancer
  • Cancer
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Cholesteryl Esters
  • Detectors
  • Isomers
  • Liquid Chromatography
  • Molecules
  • Organic Chemistry
  • Positron Emission Tomography
  • Sodium Compounds
  • Two Dimensional

Fields of Study

  • Chemistry

Readers

  • Medical Imaging.
  • Molecular and genetic basis of cancer.
  • Oncology (Cancer Research).