New Rhenium Radiopharmaceuticals for the Selective Imaging and Therapy of Breast Cancer

Abstract

This report describes progress achieved during year-i of a three year project, which seeks to develop new technology to produce rhenium radiopharmaceuticals for the diagnostic imaging and therapy of breast cancer. The discovery of a new palladium catalyzed synthetic routes to alkynl and alkenyl-linked estradiol hydrazine derivatives has been a major advance. This reaction forms a new carbon-carbon bond between ethynyl or vinyl estradiol derivatives and N'-(acyl)-4- iodophenylhydrazine, incorporating the hydrazine group in excellent yields without side reactions or degradation of the steroid. The reaction was used to prepare analogs attached to a polymeric support.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1998
Accession Number
ADA350927

Entities

People

  • Jeffrey B. Arterburn

Organizations

  • New Mexico State University

Tags

DTIC Thesaurus Topics

  • Breast Cancer
  • Carbon Carbon Composites
  • Chemistry
  • Demographic Cohorts
  • Hydrazine Derivatives
  • Hydrazines
  • Laboratory Animals
  • Materials
  • New Mexico
  • Palladium
  • Polymers
  • Precursors
  • Radiopharmaceuticals
  • Recombinant Dna
  • Resins
  • Side Reactions
  • Spectra

Fields of Study

  • Chemistry
  • Medicine

Readers

  • Breast cancer cell signaling and growth regulation.
  • Medical Imaging.
  • Organic Chemistry