IR Laser Absorption and Modeling Studies of Hydrocarbon Flames Inhibited by Candidate Halon Replacement Compounds.

Abstract

The search for viable replacement fire extinguishing compounds for the presently used Halons 1301 and 1211 has teen fully underway for some time. A successful replacement compound has to satisfy a number of criteria, including superior fire extinguishment characteristics. Recent advances in combustion science have opened up the possibility of identifying the detailed physical and chemical properties that are responsible for fire inhibition and extinction. This work indicates that each inhibiting compound exhibits a unique behavior in both experimental and computational results with respect to flame structure and adiabatic flame speed characteristics. Overall, our results indicate that the detailed chemical kinetic models have the potential for not only predicting the relative fire extinguishment properties of new Halon replacement compounds, or their mixtures, but also to predict the possible formation of toxic compounds during their use in actual fires.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1994
Accession Number
ADA351131

Entities

People

  • Andrzej W. Miziolek
  • Donald R. Burgess Jr.
  • Kevin L. McNesby
  • Phillip R. Westmoreland
  • Robert G. Daniel

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms
  • Autonomy

DTIC Thesaurus Topics

  • Absorption
  • Adiabatic Flames
  • Barometric Pressure
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Detectors
  • Flames
  • Hydrocarbons
  • Inhibition
  • Laser Diodes
  • Mass Spectrometry
  • Measurement
  • Spectra
  • Spectrometry
  • Spectroscopy
  • United States

Readers

  • Analytical Chemistry
  • Fire Suppression Systems Design.
  • Systems Analysis and Design

Technology Areas

  • Directed Energy