Macroscopically Ordered Thin Films of an Organic Salt Grown by Low Pressure Organic Vapor Phase Deposition

Abstract

We demonstrate the process of low pressure organic vapor phase deposition (LP-OVPD) for the growth of crystalline thin films of the organic charge transfer salt 4'-dimethylamino-N-methyl-4-stibazolium tosylate (DAST) on amorphous TiO2 substrates. LP-OVPD grown films exhibit polycrystallinity with long range structural ordering limited only by substrate size. Film surface coverage and macroscopic ordering are strongly determined by floe preparation of the TiO2 surface prior to growth. The morphology and ordering of the films are also found to depend on the deposition temperature and the composition of the precursor molecules. These results suggest that LP-OVPD films are of sufficient quality for use in optical waveguide and related photonic devices.

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Document Details

Document Type
Technical Report
Publication Date
Sep 30, 1998
Accession Number
ADA354570

Entities

People

  • Vladimir S. Ban

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Barometric Pressure
  • Charge Transfer
  • Crystal Structure
  • Crystals
  • Films
  • Materials
  • Molecules
  • Optical Properties
  • Phase
  • Precursors
  • Substrates
  • Surface Chemistry
  • Thin Films
  • Vacuum Deposition
  • Vapor Phases
  • Waveguides
  • X Rays

Readers

  • Materials Science and Engineering.
  • Thin Film Deposition Science.