Atmospheric Chemistry of Oxygenated Organic Compounds

Abstract

The newly revised ozone and particulate matter regulations will impact decisions on chemical substitution and formulation selection for the Air Force and DoD. Removal of toxic organics and halogenated organics from formulations has been the primary method to meet these new regulatory burdens. However, the substitutes which consist mainly of oxygenated organic compounds (alcohol, aldehydes, ketones and acetates) have poorly understood environmental impacts. To bridge this knowledge gap, investigations into the atmospheric chemistry of this useful class of compounds has begun. New information presented in this report demonstrates the wide variety of rate constants and transformation mechanisms observed. It was also observed that certain molecular structures enhance hydroxyl radical reactions. This data is important for improving the air quality assessments of new substitutes and formulations and minimizing regulatory constraints.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1998
Accession Number
ADA356188

Entities

People

  • J. R. Wells
  • J. S. Baxley
  • S. E. Wyatt
  • S. J. Markgraf

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Biomedical
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alcohols
  • Aldehydes
  • Alkanes
  • Atmospheric Chemistry
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Environment
  • Hydroxyl Radical
  • Ketones
  • Liquid Chromatography
  • Nitrogen Oxides
  • Organic Chemistry
  • Organic Compounds
  • Spectra

Fields of Study

  • Chemistry
  • Environmental science

Readers

  • Organic Chemistry
  • Systems Analysis and Design