Ionic Complexes of Conjugated Oligoquinolines
Abstract
Single crystal x-ray structures of salt complexes of oligoquinoline, 2,2'-bis(4-phenylquinoline)-1,4-phenylene (4), with p-toluenesulfonic acid, trifluoromethanesulfonic acid and a laser dye, Sulforhodamine 101 hydrate have been determined and used to study the effects of molecular packing on physical and photophysical properties of conjugated oligomer and polymers, UV-vis and emission spectra of thin films of the oligoquinoline-p-toluenesulfonate complex were also performed. These results indicate that they form an intermolecular charge-transfer complex. These complexes serve as models of quarternized polyquinolines such as the self-assembled bilayer films of polyquinoline and polystyrenesulfonic acid.
Document Details
- Document Type
- Technical Report
- Publication Date
- Nov 16, 1998
- Accession Number
- ADA356276
Entities
People
- Ashok S. Shetty
- Samson A. Jenekhe
Organizations
- University of Rochester