Study of Combustion Mechanism of Nitramine-Polymer Mixtures

Abstract

Combustion mechanism of mixtures of RDX- and HMX-copolymer (like HTPB) was investigated by microthermocouple techniques. The following parameters were found and analysed at different pressures, sample initial temperatures and oxidizer content: burning rates, burning surface temperatures, temperatures and sizes of different zones of combustion waves, thickness of heat and melted layers in solid, characteristic thickness and conductive sizes in the gas phase, heat release in solid, heat feedback from gas to solid, heat release rate in gas, macrokinetic laws of solid gasification, temperature sensitivities of burning rate and burning surface temperature. It was established that the significant heat release in solid and the weak heat feedback from gas to solid are observed for all mixtures. The control region in the combustion waves which governs the burning rate is placed in solid and in a thin gas layer close to surface. It was found that increase of the amount of oxidizer in the mixtures decreases temperature sensitivities of burning rate and burning surface temperature for both oxidizers.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1998
Accession Number
ADA359156

Entities

People

  • Anatoli A. Zenin

Organizations

  • Russian Academy of Sciences

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Burning Rate
  • Chemical Reaction Properties
  • Chemical Reactions
  • Combustion
  • Conductivity
  • Equations
  • Feedback
  • Measurement
  • Nitramines
  • Particle Size
  • Polymers
  • Sensitivity
  • Surface Temperature
  • Temperature Gradients
  • Thermal Conductivity
  • Thermocouples
  • Thickness

Readers

  • Combustion science or combustion engineering.
  • Rocket Propulsion.
  • Thermal Physics or Thermal Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene