Experimental Investigation of Polyurethane Camouflage Coating Using Dynamic Mechanical Analysis

Abstract

Three polyurethane coatings were evaluated using dynamic mechanical analysis (DMA) to investigate the relationship between dynamic mechanical properties and durability properties of coated test panels. The current polyurethane solvent-based (SOL) formulation, used as a chemical-agent-resistant camouflage top coat on all military tactical vehicles, was investigated, along with newly developed water-reducible (WR) polyurethane coatings. The WR coatings offer significantly reduced volatile organic compounds (VOC), compared to the SOL system, and thus represent environmentally compliant coatings. DMA investigations revealed that the two classes of polyurethane coatings exhibit different dynamic mechanical properties, which are attributed to different cross-linking mechanisms involved in film formation. The more uniformly cross-linked SOL coating provides the best chemical-agent resistance (CAR) but the poorest mechanical properties. Properties measured using DMA were sensitive to the degree of isocyanate to hydroxyl indexing in the WR formulations, as well as the drying time of coatings prior to evaluation. DMA investigations indicated that longer cure times at ambient temperature (6 or more months) may adversely affect the mechanical properties of the SOL system and potentially enhance CAR of the WR coating. Further studies involving aged coatings are planned.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1999
Accession Number
ADA362010

Entities

People

  • Dawn M. Crawford
  • John A. Escarsega

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Camouflage
  • Chemical Warfare Agents
  • Chemistry
  • Films
  • Isocyanates
  • Low Temperature
  • Materials
  • Mechanical Properties
  • Military Research
  • Organic Compounds
  • Polymers
  • Polyurethanes
  • Resilience
  • Resistance
  • Test And Evaluation
  • Transitions
  • Volatile Organic Compounds

Readers

  • Polymer Science and Engineering.
  • Surface Coatings Technology.