Chalcopyrite Materials Model - CM2 (Electronic Structure and Transport Properties)

Abstract

Electronic transport measurements are a method of obtaining quantitative data about a semiconductor material. The measurement of the conductivity and Hall mobilities and the subsequent analysis can determine the important processes limiting the materials usefulness. For the case of Cadmium Germanium Diarsenide (CGA), saturation at higher pump power in laser systems limits its usefulness as an optical parametric oscillator (OPO) and frequency doubler. The observed saturation has been attributed to inter- and intra-valance band transitions. The intent of the this program was to verify these saturation mechanisms using an appropriate model of CGA valance band Structure and electronic transport properties to predict related optional absorption and saturation. Modeling the transport properties of CGA should help in an understanding of the mechanisms behind this saturation. In addition, it will assist in materials improvement programs to reduce or eliminate the process(es) resulting in the observed saturation to obtain high conversion efficiencies observed at short wavelength infrared to LWIR CO2 region. The ultimate goal will he a greater than 25% conversion efficiency with high power CO2 pumps.

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Document Details

Document Type
Technical Report
Publication Date
Dec 04, 1998
Accession Number
ADA364302

Entities

People

  • Frank L. Madarasz

Organizations

  • University of Alabama in Huntsville

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Band Structures
  • Boltzmann Equation
  • Compound Semiconductors
  • Conductivity
  • Conversion
  • Crystal Lattice Vibrations
  • Energy Bands
  • Long Wavelengths
  • Materials
  • Measurement
  • Mobility
  • Phonons
  • Semiconductors
  • Short Wavelengths
  • Transport Properties
  • Valence Bands

Fields of Study

  • Materials science
  • Physics

Readers

  • Optical Physics and Photonics.
  • Semiconductor Device Technology

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Microelectronics