High-Quality C-Axis Oriented HTSC Films for Microwave Devices

Abstract

C-axis oriented HTSC films were grown by LPE on various substrates. The conditions for improving the surface flatness were systematically studied. For the achievement of interstep distances yo approx. 10 micrometers between monosteps of 12 Angstroms, as required for Tunnel devices, following requirements were estimated: undercooling delta-T = 0.17K, misfit </= 0.08%, substrate misorientation </= 0.02 deg. The defect structure and morphology of LPE films was investigated. For YBCO on (110) NGO, at growth temperature, the epitaxial strain induced by misfit can be released by misfit dislocations MD already in the first few monolayers. During cooling/oxidation, the formation of (110) twins partially relax the strain. The remaining effective strain is accommodated by crack formation. The orientational relationship between twinning/cracking related to the misfit was studied and critical thicknesses for the formation of MD and of cracks were estimated. High-quality LPE films could not be obtained on LSAT substrates, whereas same growth conditions yielded good-quality LPE films on NGO. This might be due to the striations present in LSAT which may influence nucleation and growth behavior. Solid-solutions of substrates and of HTSC allow to reduce misfit problems during growth but still the cooling/oxidation problem and lead to twinning and cracking.

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Document Details

Document Type
Technical Report
Publication Date
Jun 08, 1999
Accession Number
ADA364986

Entities

People

  • C. Klemenz

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Crystal Growth
  • Crystallization
  • Crystals
  • Dislocations
  • Epitaxial Growth
  • Heat Energy
  • High Temperature
  • Liquid Phase Epitaxy
  • Liquid Phases
  • Liquids
  • Phase
  • Phase Transformations
  • Solid Solutions
  • Substrates
  • Thickness
  • Transition Temperature
  • Transitions

Fields of Study

  • Materials science

Readers

  • Materials Science (Mechanical Engineering).
  • Superconducting Magnet Technology
  • Thin Film Deposition Science.