Reducing Air Pollutant Emissions From Solvent Multi-Base Propellant Production

Abstract

The Radford Army Ammunition Plant, Virginia, is the multi-base propellant manufacturing facility for the Department of Defense (DoD). Solvent multi-base propellant production, however, emits large quantities of volatile organic compounds (VOCs). These VOC emissions are regulated under title I of the Clean Air Act as precursors of tropospheric ozone. The pollutant stream also contains low concentrations of nitroglycerine (NG). The NG content prohibits the use of traditional air pollution control technologies because of safety concerns. This report summarizes the research of CERL and others into alternative air pollution control technologies. Bench-scale tests of sulfuric acid scrubbing, sorptive slurry biodegradation, and ultraviolet (UV) photocatalytic oxidation were conducted. The results of the UV photocatalytic oxidation tests showed the most promise based on safety, economic, and operational considerations and the remaining research effort focused on this technology. UV photocatalytic oxidation was tested on a larger scale to determine its effectiveness. This report describes the results of the larger scale testing and presents a demonstration protocol that can be applied to future full-scale work.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1999
Accession Number
ADA367284

Entities

People

  • Michael Lateulere
  • Michael R. Kemme
  • Stephen W. Maloney

Organizations

  • Construction Engineering Research Laboratory

Tags

Communities of Interest

  • Biomedical
  • Human Systems
  • Sensors
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Pollutants
  • Air Pollution
  • Chemical Synthesis
  • Chemistry
  • Environmental Protection
  • Failure Mode And Effect Analysis
  • Health Services
  • Materials Processing
  • Materials Science
  • Measurement
  • Medical Personnel
  • Nitrogen Oxides
  • Organic Compounds
  • Oxidation
  • Propellants
  • Risk Analysis
  • Volatile Organic Compounds

Fields of Study

  • Environmental science

Readers

  • Energy Conservation and Renewable Energy Engineering.
  • Groundwater Contamination Remediation.
  • Rocket Propulsion.