Optical Characterization of Rare Earth-doped Wide Band Gap Semiconductors

Abstract

Comprehensive spectroscopic studies of Er implanted GaN and in-situ Er doped AlN and GaN prepared by metalorganic molecular beam epitaxy were carried out. Each investigated sample exhibited strong 1.54 um luminescence at room temperature. it was found, however, that the incorporation and excitation schemes of Er in III Nitrides are rather complex and strongly depend on the material synthesis. For example, it was observed that high oxygen and carbon concentrations in GaN:Er greatly enhance the 1.54 um Er(3+) PL intensity under below gap excitation. Photoluminescence excitation (PLE) studies revealed that oxygen/carbon introduces a broad below gap PLE band, which provides an efficient pathway for E(3+) excitation. Under above gap excitation, however, the absolute Er(3+) PL intensity from GaN:Er samples was greatly reduced and only a weak PL dependence on the oxygen and carbon concentration was observed. Pump intensity dependent E(3+) PL studies revealed that the Er(3+) excitation efficiency for above gap pumping is reduced by a factor of 30 compared to below gap pumping. Based on the efficient below gap Er excitation a novel hybrid InGaN/GaN:Er LED operating at 1.54 um was demonstrated. Questions concerning the overall efficiency of this novel hybrid LED need to be further addressed in the future. More materials engineering focusing on improvement in the Er excitation efficiency is necessary to optimize the 1.54 um E(3+) PL from GaN:Er for practical device applications.

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Document Details

Document Type
Technical Report
Publication Date
Aug 06, 1999
Accession Number
ADA369833

Entities

People

  • Uwe Hömmerich

Organizations

  • Hampton University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Band Gaps
  • Compound Semiconductors
  • Electro-Optics
  • Energy Bands
  • Energy Levels
  • Epitaxial Growth
  • Films
  • Gallium Nitrides
  • Mass Spectrometry
  • Materials
  • Molecular Beam Epitaxy
  • Optical Properties
  • Optics
  • Semiconductors
  • Silicon Carbide
  • Spectra
  • Spectroscopy

Fields of Study

  • Materials science

Readers

  • Breast cancer cell signaling and growth regulation.
  • Molecular Photonics/Laser Physics
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics