Steroregular Aromatic Polyquinonimines and Related Polymers as Electrically Conductive, NLO-Active, Thermally Stable Polymers

Abstract

A new synthesis of high molecular weight polyaromatic quinonimines analogous to polyaniline was devised Aromatic diamines condensed with substituted p-benzoquinones or anthraquinone in presence of titanium tetrachloride/Dabco to yield a new family of soluble, orange, film forming polyaromatic quinonimines. Unlike polyaniline they were not electrically conductive. Polyaniline was alkylated by benzyl halides to form new soluble polyanilines. A cation radical mechanism was established for the oxidative polymerization of aniline. Fundamental information on the polymerization of imine monomers was obtained.

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Document Details

Document Type
Technical Report
Publication Date
Feb 14, 2000
Accession Number
ADA379042

Entities

People

  • H. K. Hall Jr.

Organizations

  • University of Arizona

Tags

Communities of Interest

  • Advanced Electronics
  • Human Systems

DTIC Thesaurus Topics

  • Alkenes
  • Butadienes
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Crystals
  • Electrical Conductivity
  • Electrical Properties
  • Films
  • Macromolecules
  • Materials
  • Molecular Weight
  • Organic Chemistry
  • Polyanilines
  • Polymerization
  • Polymers
  • Quinones

Fields of Study

  • Chemistry

Readers

  • Polymer Science and Technology