Effect of Sputtering Parameters on Tantalum Coatings for Gun Bore Applications

Abstract

Tantalum offers a number of attractive properties for gun bore coating applications, including a high melting temperature, high ductility, and an environmentally friendly deposition method. However, vapor-deposited tantalum can appear in both the characteristic body- centered-cubic phase found in the bulk material, and in a very brittle and less desirable "beta" phase. Presence of the beta phase in bore coatings is considered undesirable because of its brittleness and resulting failure as the coating is stressed. A high-rate triode sputtering system with a cylindrical coating geometry was used to produce thick tantalum coatings on 4340 steel, smooth bore cylindrical substrates. A systematic series of tests was performed to evaluate the effects of sputtering gas species (argon, krypton, xenon) and substrate temperature (100 degrees to 300 degrees C) during deposition on the phase and microstructure of the coatings. Heavier sputtering gases and higher substrate temperatures were found to promote the formation of body-centered-cubic phase tantalum coatings. Use of a movable target assembly was shown to promote the production of dense, single-phase tantalum coatings.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Aug 01, 2000
Accession Number
ADA382266

Entities

People

  • Dean W. Matson
  • Donald Windover
  • Edwin D. Mcclanahan
  • Joseph P. Rice
  • Sabrina L. Lee

Organizations

  • United States Army Armament Research, Development and Engineering Center

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Assembly
  • Beta Testing
  • Coatings
  • Diffraction
  • Diffraction Analysis
  • Environmental Protection
  • Geometry
  • Materials
  • Measurement
  • Phase Transformations
  • Physical Properties
  • Production
  • Sputtering
  • Substrates
  • Transitions
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Physics

Readers

  • Powder metallurgy of Titanium alloys.
  • Surface Coatings Technology.
  • Thin Film Deposition Science.