Ion Dynamics Related to Hypersonics

Abstract

This research has focused on systems with particular relevance to atmospheric chemistry and combustion processes In particular, the mobilities of cluster ions drifting in helium and in nitrogen buffer gas have been measured and the rotational state dependent velocity distributions and rotational alignment of the molecular nitrogen cation have been characterized. The reaction dynamics of the vibrationally excited nitrogen cation have been probed for reactions with hydrogen chloride, carbon monoxide, and nitric oxide and the multiquantum vibrational deactivation of this cation by molecular nitrogen and oxygen has been characterized. In addition, a new instrument was developed and the methyl radical products from the reactions of the parent cations of carbon monoxide and nitrous oxide with methane were detected for the first time. Atmospheric reactions, Ion molecule reactions, Transport properties, Multiquantum deactivation, Neutral product distribution, Fuel combustion

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Document Details

Document Type
Technical Report
Publication Date
Nov 27, 2000
Accession Number
ADA384750

Entities

People

  • Stephen R. Leone
  • Veronica M. Bierbaum

Organizations

  • University of Colorado Boulder

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alkanes
  • Carbon Monoxide
  • Chemical Compounds
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Dielectric Gases
  • Dynamics
  • Free Radicals
  • Gases
  • Ionization
  • Laser Induced Fluorescence
  • Mass Spectra
  • Materials Science
  • Wave Mixing

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Plasma Physics.
  • Quantum Chemistry

Technology Areas

  • Hypersonics
  • Hypersonics - Hypersonic Flight