Deposition of Ceramic Coatings by the Changed Liquid Beam Cluster Technique

Abstract

The original aim of this work was to develop a viable, on line, coating technique for oxide fibers and weaves. The coating was to be a chemically compatible, oxide (eg. hexacelsian Ba Al(2) 2SiO(8) which provided' a temperature-independent, debonding mechanism based on residual stresses developed at l59O degrees centigrade, due to a reconstructive phase transformation accompanied by a 5.6% volume contraction. However, the method adopted, the charged liquid beam cluster technique proved to be unfeasible at the current time. Attention was therefore focused onto electrophoretic deposition of oxide sols (alumina, zirconia) onto carbon-coated fibers and weaves of alumina and mullite 3Al(2)O(3).2SiO(2). However drying of films led to extensive microcracking and this method too, was found to be unsuitable. Attention was then turned to support related AFOSR work for which intermittent funding was obtained (STTR stages I and II); viz., (1) the development of mullite and YAG fibers by amorphous crystallization from a frozen, amorphous melt; (2) the elastic constants of single crystal, mullite and yttria fibers as measured by Brillouin spectroscopy to 1200 degrees centigrade; and (3) powder synthesis of oxides for matrices or deposition as coatings.

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Document Details

Document Type
Technical Report
Publication Date
Jan 10, 2001
Accession Number
ADA386679

Entities

People

  • Waltraud M. Kriven

Organizations

  • University of Illinois Urbana–Champaign

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Ceramic Materials
  • Chemical Synthesis
  • Chemistry
  • Critical Temperature
  • Crystal Structure
  • Crystals
  • Material Degradation Processes
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Materials Testing
  • Measurement
  • Modulus Of Elasticity
  • Phase Transformations

Readers

  • Materials Science and Engineering.
  • Reinforced Composite Materials
  • Thin Film Deposition Science.