Preparation of Organic Dye Gradients for Optical Limiters

Abstract

Isothermal Frontal Polymerization (IFP) is a polymerization method that propagates directionally as opposed to homogeneous polymerization. The propagation distances of Poly(Methyl Methacrylate)/Methyl Methacrylate systems can be increased by increasing the parameters of initiator decomposition rate, initiator concentration, and temperature and/or by adding a polymeric inhibitor to the bulk solution. IFP does not depend on the size of the polymeric seed, but a critical seed molecular weight must be maintained for maximum propagation. The current method of front detection is invasive and inadequate giving quantitatively irreproducible results, and thus, a new detection method is required.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 2000
Accession Number
ADA386979

Entities

People

  • John A Pojman
  • Lydia L. Lewis

Organizations

  • University of Southern Mississippi

Tags

DTIC Thesaurus Topics

  • Alkenes
  • Calcium Hydrides
  • Chemical Compounds
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Decomposition
  • Ethers
  • Explosives Initiators
  • Free Radicals
  • Inhibitors
  • Materials
  • Methacrylates
  • Molecular Weight
  • Optical Limiters
  • Organic Chemistry
  • Polymerization

Readers

  • Atmospheric Science / Meteorology, specifically Wind Wave Turbulence.
  • Medical Imaging.
  • Polymer Science and Technology