Nanocomposite Polymer Electrolytes

Abstract

Solid-state, high-density, rechargeable batteries are key to the development of several military and commercial applications, from portable electronics to electric vehicles to back-up power sources in aircraft. The objective of this program is to develop and evaluate a new generation of nanocomposite electrolytes for future military and commercial applications. One interesting class of nanocomposite electrolytes is made by intercalating polymers such as PEO between the individual layers of a layered host such as a layered silicate (Fig. 1). The resulting materials combine relatively high ambient conductivity with single ion conduction characteristics. (Note that in these nanocomposite electrolytes, 1 nm thick, negatively-charged silicate layers are separated by interlayers, which contain charge-compensating Li-cations and polymer chains. Because of their massive lateral dimensions, the silicate anions are immobile.)

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Document Details

Document Type
Technical Report
Publication Date
Nov 30, 2000
Accession Number
ADA387442

Entities

People

  • Emmanuel P. Giannelis

Organizations

  • Cornell University

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Composite Materials
  • Computer Simulations
  • Computers
  • Crystal Lattices
  • Diffraction
  • Dynamics
  • Ethylene Oxide
  • Materials
  • Materials Science
  • Molecular Dynamics
  • Monte Carlo Method
  • Nanocomposites
  • Phyllosilicates
  • Scattering
  • Simulations

Fields of Study

  • Materials science

Readers

  • Battery Technology and Engineering
  • Materials Science and Engineering.
  • Nanocomposite Materials Science

Technology Areas

  • Microelectronics