Fundamentals of High Temperature Lubrication

Abstract

A program of research has been conducted into the fundamentals of vapor phase lubrication for use in high temperature applications. The focus of the effort has been on the reaction mechanisms by which phosphates and phosphites decompose on metal surfaces to form thin lubricating films of polyphosphate glass. The results have explained the origins of the superior performance of aryl phosphates over alkylphosphates as vapor phase lubricants. In addition experiments have been conducted to probe the fundamentals of friction between single crystalline surfaces. These have revealed that friction anisotropy between crystalline metal surfaces is due to anisotropy in the work of bulk plastic deformation that occurs during sliding. They have also revealed effects of adsorbate layering at metal surfaces during sliding. Finally, study of the frictional properties of quasicrystals has revealed the role of surface oxides films in lowering the friction between quasicrystalline surfaces.

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Document Details

Document Type
Technical Report
Publication Date
Mar 31, 2001
Accession Number
ADA389303

Entities

People

  • Andrew J. Gellman

Organizations

  • Carnegie Mellon University

Tags

Communities of Interest

  • Advanced Electronics
  • C4I
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alcohols
  • Anisotropy
  • Chemical Synthesis
  • Chemistry
  • Films
  • Friction
  • High Temperature
  • Lubricants
  • Lubricating Films
  • Lubrication
  • Materials
  • Materials Science
  • Reaction Mechanisms
  • Solid Lubricants
  • Surface Chemistry
  • Turbines
  • Vapor Phases

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Mechanical Engineering/Mechanics of Materials.
  • Organic Chemistry