Microbial Characteristics of a Reactive Permeable Barrier

Abstract

Permeable reactive barriers for treatment of subsurface organic and inorganic contaminants is recent technology. Little research has been done to its potential problem areas and to measure long-term performance. Observed flow reductions and performance deterioration is typically postulated as a consequence of chemical precipitation. Thus, knowledge about biofouling of these barriers is limited. This study presents a methodology to predict the biofouling potential of permeable reactive barriers through the investigation of dominant microbial groups and using their surface thermodynamic characteristics. Predominant microbial groups were enumerated from soil cores obtained from the permeable barrier at Dover National Test Site, Dover AFB, DE. Hydrophobicity of the microorganisms and their interaction energies with the zero valent iron (ZVI) at different physiological states were quantified. Sulfate reducing bacteria (SRB), anaerobic heterotrophs and aerobic heterotrophs were detected at the site, of which SRB were the dominant group of microorganisms in the ZVI. The Gibbs free energy of SRB cells interaction with ZVI showed highest potential for adhesion at logorithmic state. Predicted observations were confirmed with batch partitioning experiments.

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Document Details

Document Type
Technical Report
Publication Date
Mar 30, 2001
Accession Number
ADA392217

Entities

People

  • Keith A. Strevett
  • M. S. Shaheed

Organizations

  • University of Oklahoma

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Accuracy
  • Adhesion
  • Air Force Research Laboratories
  • Bacteria
  • Chemical Precipitation
  • Chemical Synthesis
  • Chemistry
  • Data Analysis
  • Energy
  • Free Energy
  • Groundwater
  • Hydrophobic Properties
  • Measurement
  • Microorganisms
  • Oxidation Reduction Reactions
  • Surface Properties
  • Thermodynamic Properties

Fields of Study

  • Environmental science

Readers

  • Groundwater Contamination Remediation.
  • Theoretical Analysis.

Technology Areas

  • Biotechnology
  • Biotechnology - Bioremediation