Development of Multifunctional Perfluorinated Polymer Blends as an Active Barrier Cream Against Chemical Warfare Agents

Abstract

Chemical warfare agents (CWA's) represent a real and growing threat both to U.S. Armed Forces as well as to civilians. Within the last three decades, chemical weapons have been used by the Soviets in Cambodia (yellow rain, tricothecene mycotoxins),1 by Iraq against Iran (HD and tabun),2 and by Iraq against its own dissident Kurdish population at Halabja (HD, HCN(g))3. In the United States' experience in World War 1, almost one-third of hospitalized casualties were a result of CWA's.4 Furthermore, the 1000 casualties and 12 deaths(5) resulting from the 1995 terrorist use of sarin (GB) in Tokyo show that civilians have also become targets. in this paper we focus on protection against two classes of CWA's: nerve agents (soman, GD) and blister agents (sulfur mustard, HD).' Protection against these agents in the United States Army consists of a chemically resistant outer layer of clothing (BDO) and protective mask (M40).7 This scheme of protection allows operation in a chemically contaminated area but results in decreased performance and increased heat retention. We have investigated a material that serves as a physical barrier to CWA's and contains an active moiety to neutralize hazardous chemicals. This Active Topical Skin Protectant (aTSP) would be used in conjunction with other protective procedures. Herein we report the preparation, characterization, and evaluation of aTSP's.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2001
Accession Number
ADA395268

Entities

People

  • Ernest H. Braue Jr.
  • Stephen T Hobson

Organizations

  • United States Army Medical Research Institute of Chemical Defense

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Biomedical Research
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemical Weapons
  • Dendrimers
  • Engineering
  • Gas Chromatography
  • Inorganic Polymers
  • Mass Spectroscopy
  • Materials
  • Metal Oxides
  • Nerve Agents
  • Organic Compounds
  • Polymers
  • Spectra
  • Warfare
  • Weapons

Readers

  • Analytical Chemistry
  • Neurotoxicology
  • Political Violence and Terrorism Studies.