Biological Function of Matriptase, a Novel Trypsin-Like Protease, in Human Breast Cancer

Abstract

Matriptase is an epithelial-derived, type 2, integral membrane, serine protease. It contains an N-terminal putative transmembrane sequence, followed by multiple LDL and CUB repeats, and the C-terminal protease domain. To further understand its role in breast cancer, I have investigated its substrate specificity and its interaction with inhibitors. I showed in this report that matriptase specifically cleaves synthetic peptide after an Arg or Lys residue, and prefers small side-chain amino acid, such as Ala and Gly, at P2 site. A 3-D structure of the protease domain of matriptase was built by the homology modeling. This modeled structure was used in a structure-based screening of inhibitors. Two bis-benzamindine derivatives were developed to be both potent and selective inhibitor of matriptase. In addition, a naturally occurring trypsin inhibitor from sunflower seed was found to inhibit matriptase as well as HAI1; this inhibitor had little inhibition to thrombin and uPA. I have also shown that matriptase can activate HGF and pro-uPA. These results further support the hypothesis that matriptase acts as an upstream activator in metastasis and cancer invasion by interacting with and recruiting various factors to the site of contact between cancer and stromal cells; and by degrading or processing a broad range of substrates.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 2001
Accession Number
ADA396440

Entities

People

  • Sheau-ling Lee

Organizations

  • Georgetown University

Tags

DTIC Thesaurus Topics

  • Albumins
  • Blood
  • Breast Cancer
  • Cells
  • Chemical Synthesis
  • Chemistry
  • Enzyme Inhibitors
  • Epithelial Cells
  • Liquid Chromatography
  • Molecular Biology
  • Molecular Dynamics
  • Organic Chemistry
  • Peptide Growth Factors
  • Peptides
  • Proteins
  • Small Molecules
  • Three Dimensional

Fields of Study

  • Biology
  • Chemistry

Readers

  • Molecular and Cellular Biochemistry
  • Oncology (Cancer Research).